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于淑君 副教授 Yu,
Shuchun Joyce Associate Professor |
Date of employment:
Aug. 1, 1993
Specialty:
Organometallic, Inorganic Chemistry
TEL (O):
(886-5)
272-0411
ext. 66407
Email:
chejyy@ccu.edu.tw
Lab Webpage
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到校日期:82年8月1日
專長領域:有機金屬化學、觸媒材料化學
聯絡電話:(05)
272-0411
ext.
66407
電子信箱:chejyy@ccu.edu.tw
研究室:Rm 510
實驗室網頁
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B.S. in
Chemistry,
Chung Yuan Christian University, 1985
Ph.D. in
Chemistry,
Purdue University, 1991
Postdoc Fellow, Lawrence Berkeley National Lab & University of
California at Berkeley, 1991-1993
Associate Professor, National Chung Cheng University, 1993-
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學士
中原大學化學系理學士 (1985)
博士
美國普度大學無機化學博士 (1991)
美國勞倫斯-柏克萊國家實驗室博士後研究員
(1991-1993)
國立中正大學化學系副教授 (1993-2002)
國立中正大學化生系副教授 (2002-)
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Research Interests
Organometallic Chemistry
Design of New d-Block Metal Catalyst Systems
Transition Metals Mediated Carbon-Carbon Bond Formation and
Polymer Synthesis
Kinetic and Mechanistic Studies of Homogeneous Catalysis
Development of 2- and 3-Dimensional Polysiloxane Materials
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研究重點
有機金屬及無機錯化合物的合成及鑑定
有機金屬觸媒材料之催化反應及動力學
奈米金屬觸媒材料之催化反應性探討
無機矽酸高分子化學合成
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Selected
Publications 代表著作
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Chen, Y.-Y.; Chang, T.-C. and Yu, S. J. 2015,
"Catalytic study of a nonleaching, recoverable and recyclable Au
nanoparticle-supported palladium acetate for N-vinylation reaction of
Sulfonamides." Journal of Catalysis, submitted.
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Chang, T.-C. and Yu, S. J., "Microwave-Assisted Catalytic
Acetylation of Alcohols by Gold-Nanoparticle-Supported Gadolinium Complex."
Synth. Commun., 2015, 45(5),651–662.
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Chou, C.-C.; Wu, K.-L.; Chi, Y.; Hu, W.-P.; Yu, S. J.;
Lee, G.-H.; Lin, C.-L.; Chou, P.-T.,"Ru(II) Sensitizers with Heteroleptic
Tridentate Chelates for Dye-Sensitized Solar Cells" Angew. Chem.
Int. Ed. Engl., 2011, 50, 2054-2058.
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Young, J.-N.; Chang, T.-C.; Tsai, S.-C.; Yang, L. and Yu,
S. J. "Preparation of a nonleaching, recoverable and recyclable
palladium-complex catalyst for Heck coupling reactions by immobilization on
Au nanoparticles" Journal of Catalysis, 2010, 272,
253–261.
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Tsai, S.-C.; Lin, Y.-Y; Young, J.-N. and Yu, Shuchun
Joyce, "A Highly Efficient and Recyclable Gold Nanoparticles-Based
Palladium(II) Interphase Catalysts for Heck Coupling Reactions." Journal
of Catalysis, submitted.
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Lin, Y.-Y; Tsai, S.-C. and Yu, S. J. "Highly
Efficient and Recyclable Au Nanoparticle-Supported Palladium(II) Interphase
Catalysts and Microwave-Assisted Alkyne Cyclotrimerization Reactions in
Ionic Liquids" J. Org. Chem. 2008,
73, 4920-4928.
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Tsai, S.-C.; Fu, Y.-S.; Liao, J.-H. and Yu, S. J. "A
Versatile New Method for the Efficient Synthesis of a New Class of Aza-Based
Phosphinic Amide
Ligands via an Unusual P-C Cleavage " Helvetica Chimica Acta
2006, 89, 3007-3017.
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Chen, I.-H.; Yang, J.-N.; and Yu, S. J. "Recyclable
organotungsten Lewis Acid and microwave assisted Diels-Alder reactions in
water and in ionic liquids ". Tetrahedron 2004, 60,
11903-11909.
- Fu, Y.-S.; Tsai, S.-C.; Huang,
C.-H.; Yen, S.-Y.; Hu, W.-P.; Yu, S. J. "Kinetic Study and Theoretical
Modeling of the Diels-Alder Reactions of Cyclopentadiene and Cyclohexadiene
with Methyl Vinyl Ketone. The Effects of a Novel Organotungsten Catalyst",
J. Org. Chem., 2003, 68, 3068-3077.
- Wang, H.-S.; Yu, S. J. "Tandem
Reactions of Friedel-Crafts/Aldehyde Cyclotrimerization Catalyzed by an
Organotungsten Lewis Acid", Tetrahedron Lett. 2002, 43,
1051-1055.
- Fu, Y.-S. and Yu, S. J.,
"Immobilization of Homogeneous Palladium (II) Complex Catalysts on Novel
Polysiloxane Materials with Controllable Solubility Properties. Important
Implications for the Study of Heterogeneous Catalysis on Silica Surfaces",
Angew. Chem. Int. Ed. Engl. 2001, 40, 437-440.
- Hwang, C.-B.; Fu, Y.-S.; Lu, Y.-L.;
Jang, S.-W.; Chou, P.-T.; Wang, C. R. C. and Yu, S. J., "Synthesis,
Characterization and Highly Catalytic Reactivity of Suspended Palladium
Nanoparticles", Journal of Catalysis, 2000, 195,
336-341.
- Kuo, C.-Y.; Fuh, Y.-S.; Chaen,
M.-C.; Yu, S. J., "Homogeneous Diels-Alder Catalysis by Organotungsten Lewis
Acid Containing Tris(2-pyridyl)phosphine Ligand", Tetrahedron Letters,
1999, 40, 6451-6454.
- Kuo, C.-Y.; Fuh, Y.-S.; Shiue,
J.-Y.; Lee, G.-H.; Peng, S.-M.; Yu, S. J, "Synthesis and Chemistry of
Tris(2-pyridyl)phosphine Complexes of Group VI Transition Metals. X-ray
Structural Studies of the Molybdenum Complexes", J. Organomet. Chem.,
1999, 588, 260-267.
- Yu, S. J.; Felter, L.; Rothwell, I.
P., "Intramolecular dehydrogenation of Alkyl Groups at Niobium Aryloxide
Centers: Bonding and Reactivity of the Ensuing Niobacyclopropane Ring",
Organometallics 1996, 15, 21.
- Yu, J. S. ; Ankianiec, B. C.;
Rothwell, I. P., "Highly Stereoselective ( all cis ) Catalytic
Hydrogenation of Polynuclear Aromatic Hydrocarbons by Group 5 Metal
Aryloxide Compounds", J. Am. Chem. Soc. 1992, 114,
1927.
- Yu, J. S.; Rothwell, I. P.,
"Catalytic Hydrogenation of Aryl-Phosphines by Niobium Aryloxide Compounds:
High Yield and Efficient Synthesis of Cyclohexyl-Phosphine Ligands", J.
Chem. Soc., Chem. Commun. 1992, 632.
- Yu, J. S.; Fanwick, P. E.; Rothwell,
I. P., "The Structure of a Tetrahedral Niobium Oxo Compound
[Nb(OC6H3Ph2-2,6)3(O)]", Acta. Cryst. 1992, 48, 1759.
- Yu, J. S.; Chesnut, R. W. ; Jacob,
G. G.; Fanwick, P. E.; Rothwell, I. P., "A Mechanistic Study of the
cyclometallation of o-Arylphenoxide Ligands at Group 5 Metal Centers",
Organometallics 1991, 10, 321.
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Yu, J. S. ; Fanwick, P. E. ; Rothwell, I. P., "Intramolecular
Alkane Dehydrogenation and Functionalization at Niobium Metal Centers",
J. Am. Chem. Soc. 1990, 112, 8171.
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